I'll admit that I was a hard-core 2-channel guy for the last 20 years. But it was when I heard "DTB300's" astounding multichannel setup that I became a convert to 5.1 systems, ESPECIALLY for multi-channel concert DVDs. He kindly hosted a Martin Logan Listening Day at his house a few years ago, and I believe it was the "Eagles" convert video called "Hell Freezes Over", with it's 5.1 DTS soundtrack that nailed it for me. After owning just 2 Martin Logan Sequels for almost 20 years, I embarked on a mission to collect an entirely ML 5.1 setup, and within the year, I'd bought a Logos center channel speaker, and a pristine pair of Scenarios for the rears. My rig sounds different from "DTB300's", but it's still pretty good in it's own right.
I've moved twice since then, and my rig has gone through several different re-designs. Currently I have a scaled-down 5.1 rig (Scenarios as front L/R and Logos as center, with small "bookshelf" speakers as rears) and my Sequels are back in a dedicated 2-ch rig. But I'll admit that I am a DEDICATED 5.1 believer when it comes to movies and concert DVDs, ESPECIALLY the newer stuff on Blu-Ray, which sounds a gazillion times better than standard DVDs...
If you watch a lot of concert DVDs, or are considering getting a Blu-Ray player, I would tell you that 5.1 is NOT an option--it's pretty much a REQUIREMENT to get the most out of your video experience. A properly set up .1 system enhanced the movie experience tremendously, and can make concert videos "the next best thing to being there". And if you have cable or satellite, there is a LOT of programming being broadcast these days that is also in 5.1. If you get PBS in High Def, the concert programs are almost all in Dolby 5.1--Mountain Stage, Austin City Limits, etc. I've seen a LOT of great concerts on ACL recently that had beautiful camera work, and REALLY fine soundtracks too.
Good luck in your pursuit of this hobby. It can lead to a LOT of research, work, and tweeking, but in the end, a well-set-up 5.1 rig is a great thing, IMO...
--Richard